PDF

Keywords

electric arc furnace dust
zinc
hydrometallurgy
sulfuric acid leaching
electrolysis
secondary resources
comprehensive processing

How to Cite

HYDROMETALLURGICAL PROCESSING OF EAF DUST: ZINC EXTRACTION AND RECYCLING IRON RESIDUE IN STEELMAKING. (2026). Mining Bulletin of Uzbekistan, 1(104), 16-20. https://journal.nsumt.uz/academy/index.php/MBU/article/view/87

Abstract

Electric arc steel smelting furnace dust (EAP dust) is one of the most problematic waste in modern metallurgy from an ecological and technological point of view due to its high dispersity, high content of zinc, lead, and other associated elements. In recent years, as a result of the increase in the share of zinc-containing secondary raw materials in the metal charge, the amount of this dust has also increased. In this study, a hydrometallurgical method of complex processing of PE PE dust based on sulfuric acid leaching was considered. A spent sulfuric acid electrolyte containing H2SO4 (120-160 g/l) and Zn (30-50 g/l) was used as the solvent reagent. The leaching process was carried out at a temperature of 60-65 °C, in a solid-liquid ratio of 1:6, for 120-240 minutes. The research results showed that zinc-containing phases accelerate the dissolution kinetics, reduce energy consumption, and provide the possibility of effective extraction of zinc from the solution and subsequent obtaining the cathode metal by electrolysis. In addition, it has been substantiated that the iron-containing residue formed after leaching can be re-turned to the steelmaking process as a charge additive. The proposed technology is a resource-saving, energy-efficient, and environmentally friendly alternative to traditional pyrometallurgical methods of processing EAP dust. This approach serves the implementation of the principles of a circular economy through the processing of metallurgical waste, the restoration of zinc, and the return of iron components to production.

PDF

References

1. Kozlov, P. A., Povysheva, E. V., Zolkina, A. V., & Vorobiev, A. G. (2009). Current state and prospects of Waelz process application for EAF dust treatment. Non-Ferrous Metals, 7, 36–40.

2. Havlík, T., Souza, B. V., Bernardes, A. M., Schneider, I. A. H., & Miskufová, A. (2006). Hydrometallurgical processing of carbon steel electric arc furnace dust. Journal of Hazardous Materials, 135, 311–318. https://doi.org/10.1016/j.jhazmat.2005.11.067

3. Peters, M. A. (1990). Process for recovery of zinc oxide from steelmaking dust (U.S. Patent No. 4,071,357).

4. Lytaeva, T. A., & Pashkevich, M. A. (2014). Utilization of powdered zinc-iron-containing wastes from mining and processing enterprises. Mining Informational and Analytical Bulletin, 4, 330–333.

5. Jha, M. K., Kumar, V., & Singh, R. J. (2001). Review of hydrometallurgical recovery of zinc from industrial wastes. Resources, Conservation and Recycling, 33, 1–22. https://doi.org/10.1016/S0921-3449(01)00094-3

6. Dutra, A. J. B., Paiva, P. R. P., & Tavares, L. M. (2006). Alkaline leaching of zinc from electric arc furnace steel dust. Minerals Engineering, 19, 478–485. https://doi.org/10.1016/j.mineng.2005.08.013

7. Xia, D. K., Pickles, C. A., & Jiang, T. (2014). Kinetics of zinc ferrite leaching in sulfuric acid. Hydrometallurgy, 142, 103–109. https://doi.org/10.1016/j.hydromet.2013.12.003

8. Reddy, B. R., Kumar, J. R., & Park, K. H. (2004). Studies on dissolution of zinc ferrite. International Journal of Mineral Processing, 72, 373–381. https://doi.org/10.1016/S0301-7516(03)00119-6

9. Mombelli, D., Mapelli, C., Barella, S., & Gruttadauria, A. (2016). Ammonium chloride leaching of electric arc furnace dust. Metallurgical Research & Technology, 113, 203. https://doi.org/10.1051/metal/2016014

10. Soucy, G., Perrault, G., & Baril, J. (2000). Autoclave leaching of zinc concentrates and secondary materials. Hydrometallurgy, 56, 23–38. https://doi.org/10.1016/S0304-386X(00)00083-6

11. Zhang, Y., Guo, Y., & Han, B. (2018). Pressure leaching of zinc from EAF dust. Transactions of Nonferrous Metals Society of China, 28, 2246–2253. https://doi.org/10.1016/S1003-6326(18)64838-1

12. Jorgensen, F. R. A. (2013). Recycling of electric arc furnace dust. Ironmaking & Steelmaking, 40, 576–582. https://doi.org/10.1179/1743281213Y.0000000125

13. Agatzini-Leonardou, S., Oustadakis, P., Tsakiridis, P. E., & Markopoulos, C. (2004). Recovery of metals from electric arc furnace dust. Journal of Hazardous Materials, 104, 31–40. https://doi.org/10.1016/j.jhazmat.2003.07.006

14. Li, Y., Li, J., & Zhang, S. (2020). Sustainable processing of steelmaking dust: A review. Journal of Cleaner Production, 250, 119486. https://doi.org/10.1016/j.jclepro.2019.119486

15. Pickles, C. A. (2008). Thermodynamic analysis of zinc-containing phases in EAF dust. Minerals Engineering, 21, 1256–1260. https://doi.org/10.1016/j.mineng.2008.03.012

16. Abanades, J. C., Arias, B., & Lyngfelt, A. (2019). Zinc recovery routes from metallurgical wastes. Chemical Engineering Journal, 359, 131–143. https://doi.org/10.1016/j.cej.2018.11.070

17. Zhang, L., & Ostrovski, O. (2001). Zinc behavior during steelmaking processes. Metallurgical and Materials Transactions B, 32, 1047–1054. https://doi.org/10.1007/s11663-001-0092-5

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Copyright (c) 2026 Ilhamov, M.A., Munosibov, Sh.M., Matkarimov, S.T., Maksudov, S.A. (Muallif)

Downloads

Download data is not yet available.